In classical physics, a spring can be seen as a device that stores potential energy, specifically elastic potential energy, by straining the bonds between the atoms of an elastic material.
Hooke's law of elasticity states that the extension of an elastic rod (its distended length minus its relaxed length) is linearly proportional to its tension, the force used to stretch it. Similarly, the contraction (negative extension) is proportional to the compression (negative tension).
This law actually holds only approximately, and only when the deformation (extension or contraction) is small compared to the rod's overall length. For deformations beyond the elastic limit, atomic bonds get broken or rearranged, and a spring may snap, buckle, or permanently deform. Many materials have no clearly defined elastic limit, and Hooke's law can not be meaningfully applied to these materials. Moreover, for the superelastic materials, the linear relationship between force and displacement is appropriate only in the low-strain region.
Hooke's law is a mathematical consequence of the fact that the potential energy of the rod is a minimum when it has its relaxed length. Any smooth function of one variable approximates a quadratic function when examined near enough to its minimum point as can be seen by examining the Taylor series. Therefore, the force โ which is the derivative of energy with respect to displacement โ approximates a linear function.